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Crystal structure of trans -1-{2-[4-(dimethylamino)phenyl]ethyl}-4-[2-(pyren-1-yl)ethyl]cyclohexane

机译:反式-1- {2- [4-(二甲基氨基)苯基]乙基} -4- [2-(吡啶-1-基)乙基]环己烷的晶体结构

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摘要

The title compound, C$_{34}$H$_{37}$N, is a pyrene derivative in which the pyrene ring system is linked to an ethylcyclohexane unit which, in turn, carries a [4-(dimethylamino)phenyl]ethyl substituent in the para position. The central cyclohexane ring has a chair conformation, with the exocyclic C—C bonds inequatorial orientations. The benzene ring is inclined to the mean plane of the pyrene ring system [maximum deviation =0.038 (4) Å] by 14.84 (15) ̊ . In the crystal, molecules are linked by C—H ...$\pi$ interactions, forming chains propagating along [010]. The crystal was refined as a non-merohedral twin [domain ratio = 0.9989 (4):0.0011 (4)].
机译:标题化合物C $ _ {34} $ H $ _ {37} $ N是is衍生物,其中the环系统与乙基环己烷单元相连,乙基环己烷单元又带有[4-(二甲基氨基)苯基对位上有]乙基取代基。中央环己烷环具有椅子构型,环外CC键位于赤道方向。苯环相对于the环系统的平均平面倾斜[最大偏差= 0.038(4)Å] 14.84(15)̊。在晶体中,分子之间通过CH ... \ pi $相互作用连接,形成沿[010]传播的链。晶体被细化为非体面孪晶[畴比= 0.9989(4):0.0011(4)]。

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